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81.
Ren‐Qi Wang Katharina Druckenmüller Gereon Elbers Klaus Guenther Jean‐Philippe Croué 《Journal of mass spectrometry : JMS》2014,49(2):154-160
The composition and physiochemical properties of aquatic‐phase natural organic matter (NOM) are most important problems for both environmental studies and water industry. Laser desorption/ionization (LDI) mass spectrometry facilitated successful examinations of NOM, as humic and fulvic acids in NOM are readily ionized by the nitrogen laser. In this study, hydrophobic NOMs (HPO NOMs) from river, reservoir and waste water were characterized by this technique. The effect of analytical variables like concentration, solvent composition and laser energy was investigated. The exact masses of small molecular NOM moieties in the range of 200–1200 m/z were determined in reflectron mode. In addition, spectra of post‐source‐decay experiments in this range showed that some compounds from different natural NOMs had the same fragmental ions. In the large mass range of 1200–15 000 Da, macromolecules and their aggregates were found in HPO NOMs from natural waters. Highly humic HPO exhibited mass peaks larger than 8000 Da. On the other hand, the waste water and reservoir water mainly had relatively smaller molecules of about 2000 Da. The LDI‐MS measurements indicated that highly humic river waters were able to form large aggregates and membrane foulants, while the HPO NOMs from waste water and reservoir water were unlikely to form large aggregates. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
82.
Xiaokai Ding Dong Luo Jiaxiang Cui Huixian Xie Qingqing Ren Zhan Lin 《Angewandte Chemie (International ed. in English)》2020,59(20):7778-7782
Voltage decay and capacity fading are the main challenges for the commercialization of Li‐rich Mn‐based layered oxides (LLOs). Now, a three‐in‐one surface treatment is designed via the pyrolysis of urea to improve the voltage and capacity stability of Li1.2Mn0.6Ni0.2O2 (LMNO), by which oxygen vacancies, spinel phase integration, and N‐doped carbon nanolayers are synchronously built on the surface of LMNO microspheres. Oxygen vacancies and spinel phase integration suppress irreversible O2 release and help lithium ion diffusion, while N‐doped carbon nanolayer mitigates the corrosion of electrolyte with excellent conductivity. The electrochemical performance of LMNO after the treatment improves significantly; the capacity retention rate after 500 cycles at 1 C is still as high as 89.9 % with a very small voltage fading rate of 1.09 mV cycle?1. This three‐in‐one surface treatment strategy can suppress the voltage decay and capacity fading of LLOs. 相似文献
83.
We discuss model-independent constraints on spin observables in exclusive and inclusive reactions, with special attention to the case of photoproduction. 相似文献
84.
We study the discrete-time evolution of a recombination transformation in population genetics. The transformation acts on a product probability space, and its evolution can be described by a Markov chain on a set of partitions that converges to the finest partition. We describe the geometric decay rate to this limit and the quasi-stationary behavior of the Markov chain when conditioned on the event that the chain does not hit the limit. 相似文献
85.
We study spectral distortions of diffuse ultra-high energy (UHE) neutrino flavour fluxes resulting due to physics beyond the Standard Model (SM). Even large spectral differences between flavours at the source are massaged into a common shape at earth by SM oscillations, thus, any significant observed spectral differences are an indicator of new physics present in the oscillation probability during propagation. Lorentz symmetry violation (LV) and neutrino decay are examples, and result in significant distortion of the fluxes and of the well-known bounds on them, which may allow UHE detectors to probe LV parameters, lifetimes and the mass hierarchy over a broad range. 相似文献
86.
We analyze the radiative leptonic Be decay B-→τ-(v)τγ in the Standard Model and the twoHiggs-doublet model using the non-relativistic constituent quark model.The results confirm that this channel is experimentally promising in view of the large number of Bc mesons which are expected to be produced at future hadron facilities.We also find that this decay is sensitive to the parameters of the two-Higgs-doublet model,and it can be tested in future experiments. 相似文献
87.
LIU Xiang 《中国物理C(英文版)》2009,33(6)
In this talk, we briefly review the experimental status of newly observed charmed hadrons during the past years. Then we introduce the theoretical progresses on these charmed hadrons, especially our studies on the strong decays of new charmed hadrous during the past one year. 相似文献
88.
G. Brunner 《Isotopes in environmental and health studies》2013,49(12):420-424
Modern radiometric analytics demands a complex consideration of nuclear and electron shell processes, if more pretentious aims are envisaged. As an example the small variation of decay rates of radionuclides presents possibilities for information on chemical situations of decaying atoms. In principle this phenomenon is well known since many years, but now the situation is such that, e.g. in 99mTc internal conversion, a full agreement of the difficult experiments and the respective theory was established. The secondary emission of X-rays as a consequence of high excitation of electron shells in combination with nuclear transitions supplies another example for a methodical progress of radiometry. Investigations on 51Cr as an electron capture nuclide have shown that chemically induced variations of the Kα to Kβ X-ray intensity ratio is at least qualitatively understood. 相似文献
89.
应用边界层积分法,研究锥形喷嘴入口区域中湍动涡流的发展.球面坐标系中的控制方程,通过边界层的假定得到简化,并对边界层进行了积分.应用4阶Adams预测校正法求解该微分方程组.入口区域的切向和轴向速度,分别应用自由涡流和均匀速度分布来表示.由于缺乏收缩喷嘴中涡流的实验数据,需要用数值模拟对该发展模式进行逆向验证.数值模拟的结果证明,该解析模型在预测边界层参数中的能力,例如边界层的生长、剪切率和边界层厚度,以及不同锥度角时的涡流强度衰减率等.为所提出的方法引进一个简明而有效的程序,用以研究几何形状收缩设备内的边界层参数. 相似文献
90.
We study the phase probability distribution of a three-level atom interacting with a cavity field in the presence of two-photon detuning and decoherence. Anabiosis of the phase probability distribution is observed due to the presence of the Stark shift. The simulation demonstrates that there is an enhancement of the phase sensitivity as soon as the two-photon detuning is considered. The W-Wigner function is also examined and it is shown that the nonclassical effect is apparent, however, for a small value of the decoherence factor. 相似文献